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Leak of butadiene

  • FRANCE
In a synthetic rubber plant, a valve broke on a 12.5 m³ tank half filled with butadiene; 5 m³ of the substance were released into the atmosphere. Production was halted and the internal emergency plan activated (under the scenario of[...]
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Packing of a Styrene / AcryloNitrile copolymerisation reactor

  • FRANCE
At 10.40 pm, during a styrene/acrylonitrile copolymerisation reaction in a plastics manufacturing plant, the operator in the control room detected an abnormal temperature increase to 125 °C on one of the 75-m³ reactors. The visual display screen in the control[...]
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Explosion followed by a fire on a production line

  • FRANCE
A tank undergoing cleaning exploded after a 15-day production run. Along with a damaged drum dryer, the tank had been collecting washing water with an excess concentration of 2'-azobis (2 methylbutyronitrile) - AIVN (a by-product of hydrazine hydrate). In anticipating[...]
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Explosion of a reactor

  • FRANCE
At 10:30 pm in a fine chemistry plant, a reactor underwent a pressure rise during chlorination of alcohol using thionyl chloride (SOCl2). This slightly exothermic reaction took place in a solvent medium (1,2 dichloroethane, or DCE) and under a slight[...]
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Hydrogen explosion and fire

  • FRANCE
An explosion and fire occurred at night inside a workshop dedicated to toluene di-amine (TDA) synthesis by means of hydrogenating dinitrotoluene (DNT) in the presence of Raney nickel; the workshop had been taken offline for scheduled maintenance. Internal fire-fighters had[...]
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Release of hydrochloric acid

  • FRANCE
A reaction between cyanuric chloride and sulphanilic acid ran away inside a fine chemistry unit. Water, sulphanilic acid and cyanuric chloride were loaded into an 8,000-litre reactor. According to the new operating protocol, 1 tonne of ice was supposed to[...]
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Transfer of chemical effluents from a tank to a road tank

  • FRANCE
While transferring concentrated liquid waste inside a chemical plant, a tanker lorry driver died. He arrived at 9:30 am at the reception area and was joined in the transfer zone by the plant's safety engineer. The transfer from tank to 2[...]
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Explosion of an underground explosive storage

  • SUISSE
Around 4:10 pm, six people were killed by the explosion of nearly 300 tonnes of expired munitions and production wastes inside the "Steingletscher" underground storage, located on the slope of the Susten pass facing Bern. The explosion, whose TNT equivalent[...]
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